(1) Microstructure characterization and magnetic behavior of NiAlxFe2_xO4 and Ni1_yMnyAl0.2Fe1.8O4 ferrites

 

Abstract :

NiAlxFe2_xO4 and Ni1_yMnyAl0.2Fe1.8O4 ferrites were prepared by the conventional ceramic method and were characterized by X-ray diffraction, scanning electron microscopy, and magnetic measurements. The single spinel phase was confirmed for all prepared samples.

A proper explanation of data is possible if the Al3+ ions are assumed to replace Fe3+ ions in the A and B sites simultaneously for NiAlxFe2_xO4 ferrites, and if the Mn2+ ions are assumed to replace Ni2+ ions in the B sites for Ni1_yMnyAl0.2Fe1.8O4 ferrites. Microstructural factors play an important role in the magnetic behavior of Ni1_yMnyAl0.2Fe1.8O4 ferrites with large Mn2+ content.